The stabilization of coordination compounds due to chelation is called the chelate effect. Which of the following is the most stable complex species?

  • A
    $[Fe(CO)_5]$
  • B
    $[Fe(CN)_6]^{-3}$
  • C
    $[Fe(C_2O_4)_3]^{-3}$
  • D
    $[Fe(H_2O)_6]^{+3}$

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The stepwise stability constants of a complex are given below. What is its overall reaction stability constant $\beta_4$ ?
$M + L \rightleftharpoons ML ; K_1 = 1.0 \times 10^4$
$ML + L \rightleftharpoons ML_2 ; K_2 = 1.0 \times 10^3$
$ML_2 + L \rightleftharpoons ML_3 ; K_3 = 1.0 \times 10^3$
$ML_3 + L \rightleftharpoons ML_4 ; K_4 = 1.0 \times 10^2$
(Overall reaction : $M + 4L \rightleftharpoons ML_4$)

$AgCl$ dissolves in ammonia solution giving

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